Given two polygons
we say that
where
Example
Consider the rectangle
The answer is NO, because even if the angles of each apex are equal, the reasons of the sides are different since the square has all the equal sides while the rectangle has the sides equal two by two.
This leads us to say that a square will always be similar to another square. More generally, a regular polygon will always be similar to the same regular polygon since the angles will be equal and the sides will be proportional.